Yes, a 100 watt solar panel can charge a 12V battery. In fact, one 100Ah 12V battery can be fully charged by a 100 watt 12V solar panel. However, charging larger batteries or multiple batteries may take a longer time.
With a 100 watt solar panel, you could use one 85Ah 12V battery. But your best option would be to use one 100Ah 12V battery. If you want to make your battery last long you should avoid letting the battery reach 50% discharge.
When a solar panel charges a battery, around 15% of the energy may be lost. Thus, if the solar panel is 85% efficient the battery will receive 600 x 0.85 = 510 watts. Let us suppose you have a 12V battery and it is 50% charged. To fully charge the battery you need 510 x 2 = 1020 watts. Now you need to convert 1020 watts into amp hours.
This means that a 100W solar panel can charge a lead-acid battery at a rate of 2 Amps, and can charge a lithium-ion battery at a rate of 10 Amps. The amount of time it takes to charge a battery will also depend on the type of battery being used. How fast will a 100w solar panel charge a 12v battery?
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